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Properties of Motor Oil
By Phil White
Most motor oils are made from a heavier, thicker petroleum hydrocarbon base stock derived from crude oil, with additives added as needed to improve the properties. One of the most important properties of motor oil in maintaining a lubricating film between moving parts is its viscosity. In layman's terms, the viscosity of a liquid can be thought of as its "thickness" or a quantity of resistance to flow. The viscosity must be high enough to maintain a satisfactory lubricating film, but low enough that the oil can flow around the engine parts satisfactorily to keep them well coated under all conditions. The viscosity index is a measure of how much the oil's viscosity changes as temperature changes. A higher viscosity index indicates the viscosity changes less with temperature than a lower viscosity index.
Another important property of motor oil is its pour point, which is indicative of the lowest temperature at which the oil could still be poured satisfactorily. The lower the pour point temperature of the oil, the more desirable the oil is when starting up at cold temperature.
Oil is largely composed of hydrocarbons, which can burn if ignited. Still another important property of motor oil is its flash point; the lowest temperature at which the oil gives off vapors which can ignite. It is, of course, dangerous for the oil to ignite and burn, so a high flash point is desirable. At a petroleum refinery, fractional distillation to separate crude oil fractions removes the volatile components, which more easily ignite, from the motor oil fraction; therefore, increasing the oil's flash point.
Another test done on oil is Total Base Number (TBN), which is a measurement of reserve alkalinity of an oil for neutralizing acids. The resulting quantity is determined as mg KOH/(gram of lubricant). Analogously, Total Acid Number (TAN) is the measurement of a lubricant’s acidity content. Other tests include zinc, phosphorus, or sulfur content, and testing for excessive foaming.
Most commercial oils have a minimal amount of zinc dialkyldithiophosphate as an anti-wear additive to protect contacting metal surfaces with zinc in case of metal to metal contact.
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